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Beilstein J. Org. Chem. 2005, 1, No. 2, doi:10.1186/1860-5397-1-2
Graphical Abstract
Scheme 1:
Scheme 2:
Scheme 3:
Figure 1: Diastereoselective substitution of the N,O acetal 12
Scheme 4:
Figure 2: Diastereoselective Luche reduction of piperidinones
Scheme 5:
Figure 3: Diastereoselective dihydroxylation of unsaturated piperidines
Figure 4: Diagnostic nOe observations for the piperidine 22A
Figure 5: Diagnostic nOe observations for the piperidines 22C and 22D
Scheme 6:
Figure 6: Stereoselectivity of two-directional Luche reductions
Scheme 7:
Scheme 8:
Figure 7: Two-directional functionalisation by diastereoselective dihydroxylation